Author: Fred F. Ferri, MD
Vitamins are organic compounds that cannot be synthesized by humans but are required as nutrients in minute amounts for normal metabolism. Vitamins have several different functions: They may regulate cell growth and differentiation, as catalysts, as antioxidants, and as coenzymes. Vitamins are classified as either fat soluble (vitamins A, D, E, K) or water soluble (B group of vitamins and C). Deficiency of most vitamins is rare in Western countries. Certain groups may be prone to vitamin deficiency, and these are discussed here. Vitamin D deficiency is discussed in a separate topic.
| ICD-10CM CODES | |||
| E50 | Vitamin A deficiency | ||
| E51 | Thiamine deficiency | ||
| E53 | Deficiency of other B group vitamins | ||
| E55 | Vitamin D deficiency | ||
| E56 | Other vitamin deficiencies | ||
| E56.0 | Deficiency of vitamin E | ||
| E56.1 | Deficiency of vitamin K | ||
| E53.0 | Riboflavin deficiency | ||
| E52 | Niacin deficiency [pellagra] | ||
| E53.1 | Pyridoxine deficiency | ||
| E53.8 | Deficiency of other specified B group vitamins | ||
| E54 | Ascorbic acid deficiency | ||
Deficiency can occur in all age groups but is most common in the elderly.
Fig. 1 shows environmental and nutritional factors in disease.
Figure E2 Spinal cord in cobalamin deficiency.

The cross-section of the spinal cord stained with Luxol blue shows demyelination of the dorsal columns (a) and early demyelination of the lateral columns (b).
(From Hoffman R et al: Hematology, basic principles and practice, ed 8, Philadelphia, 2023, Elsevier.)

A, Perifollicular hemorrhages. B, Corkscrew hairs with perifollicular hyperkeratotic papules.
(Modified from Lipner S: A classic case of scurvy, Lancet 392[10145]:431, 2018.)

The knee shows widened metaphyses with spurs and reduced bone density. The ossific centers have a typical "white pencil" outline. Faint periosteal reaction is visible in the distal femur secondary to periosteal hemorrhage. The end plate is still well defined, and the physis is not widened (compared with rickets). Fractures are rare.
(From Pope TL et al: Musculoskeletal imaging, ed 2, Philadelphia, 2014, Saunders.)
Table 1 summarizes clinical clues in identifying vitamin deficiency. A stepwise approach to the diagnosis of cobalamin and folate deficiency is summarized in Table 2. False positive and false negative test results are explained in Table 3.
TABLE 1 Clinical Clues in Identifying Vitamin Deficiency
| Clinical Features | Causes and Diagnosis | Treatment and Notes |
| Vitamin A deficiency | ||
| Vitamin B12 deficiency | ||
| Vitamin B6 (pyridoxine) deficiency | ||
| ||
| Vitamin B2 (riboflavin) deficiency | ||
| Vitamin supplementation | ||
| Vitamin B1 (thiamine) deficiency | ||
| Thiamine supplementation | ||
| Vitamin C deficiency (scurvy) | ||
| Low dietary intake | ||
| Iodine deficiency | ||
| Hypothyroidism | Improve dietary intake | |
| Niacin deficiency (pellagra) | ||
| Replacement treatment | ||
| Zinc deficiency | ||
| Low dietary intake | Zinc supplementation | |
| Vitamin E deficiency | ||
| Vitamin K deficiency | ||
| Vitamin K supplementation | ||
| Vitamin D deficiency | ||
|
|
INR, International normalized ratio; RDA, recommended dietary allowance; PT, prothrombin time.
From Talley NJ et al: Essentials of internal medicine, ed 4, Chatswood, NSW, 2021, Elsevier Australia.
TABLE 2 Stepwise Approach to the Diagnosis of Cobalamin and Folate Deficiency
| Megaloblastic Anemia or Neurologic-Psychiatric Manifestations Consistent With Cobalamin Deficiency Plus Test Results on Serum Cobalamin and Serum Folate | |||
| Cobalamina (pg/ml) | Folateb (ng/ml) | Provisional Diagnosis | Proceed With Metabolites?c |
| >300 | >4 | Cobalamin or folate deficiency is unlikely | No |
| <200 | >4 | Consistent with cobalamin deficiency | No |
| 200-300 | >4 | Rule out cobalamin deficiency | Yes |
| >300 | <2 | Consistent with folate deficiency | No |
| <200 | <2 | Consistent with combined cobalamin plus folate deficiency | Yes |
| >300 | 2-4 | Consistent with (1) folate deficiency or (2) an anemia unrelated to vitamin deficiency | Yes |
| Test Results on Metabolites: Serum Methylmalonic Acid and Total Homocysteine | |||
| Methylmalonic Acid (Normal, 70-270 nM) | Total Homocysteine (Normal, 5-14 μM) | Diagnosis | |
| Increased | Increased | Cobalamin deficiency confirmed; folate deficiency still possible (i.e., combined cobalamin plus folate deficiency possible) | |
| Normal | Increased | Folate deficiency is likely | |
| Normal | Normal | Cobalamin and folate deficiency is excluded | |
a Serum cobalamin levels: abnormally low, less than 200 pg/ml; clinically relevant low-normal range, 200-300 pg/ml.
b Serum folate levels: abnormally low, less than 2 ng/ml; clinically relevant low-normal range, 2-4 ng/ml.
c Any frozen-over sample from serum folate/cobalamin determination can be subjected to metabolite tests.
From Hoffman R et al: Hematology, basic principles and practice, ed 8, Philadelphia, 2023, Elsevier.
TABLE 3 Serum Cobalamin: False-Positive and False-Negative Test Results
| Falsely Low Serum Cobalamin in the Absence of True Cobalamin Deficiency | |||
| Folate deficiency (one-third of patients) Multiple myeloma TCI deficiency Megadose vitamin C therapy | |||
| Falsely Raised Cobalamin Levels in the Presence of a True Deficiencya | |||
| Cobalamin binders (TCI and II) increased (e.g., myeloproliferative states, hepatomas, and fibrolamellar hepatic tumors) TCII-producing macrophages are activated (e.g., autoimmune diseases, monoblastic leukemias and lymphomas) Release of cobalamin from hepatocytes (e.g., active liver disease) High serum anti-IF antibody titer |
IF, Intrinsic factor; TC, transcobalamin.
a Although a low serum cobalamin level is not synonymous with cobalamin deficiency, 5% of patients with true cobalamin deficiency have low-normal cobalamin levels, a potentially serious problem because the patients underlying cobalamin deficiency will progress if uncorrected.
From Hoffman R et al: Hematology, basic principles and practice, ed 8, Philadelphia, 2023, Elsevier.
General initial laboratory tests include:
Specific tests may be considered in the following cases:
Most of the vitamins are available over the counter individually or in different multivitamin formulations.